You can enable/disable synchronous replication at any time and the keepers will reconfigure themselves.
You can do this with stolonctl
.
Assuming that you cluster name is mycluster
and etcd is listening on localhost:2379:
stolonctl --cluster-name=mycluster config patch '{ "synchronousreplication" : true }'
stolonctl --cluster-name=mycluster config patch '{ "synchronousreplication" : false }'